I have just been playing around and noticed that when I set the HiDPI Mode in the Advanced settings to DPI Unaware,

and also set my Main Display Monitor to a scale of 125% in my Windows Display settings like so,

I get the Remote Main View to work!!!
The only problem is that while the Monitor view is nicely displayed as below,

the Remote Main View displays with some amount of offset, making text disappear of the screen as seen below
This I believe is down to the 125% scale factor being applied to the screen being used as the Main Display in Windows Display settings.
The screen I am using as Main Display has a resolution of 1680 x 1050. However, OpenLP's representation of it is 1344 x 840. See Screen 3 circled in this screenshot
In summary, without the 125% scaling in Windows, I only get the desktop in the Remote Main View. The resulting Remote Main View with the 125% scaling however, is quite unusable.
I hope with this new information, someone may be able to work out what is going with what seems to be a really obscure edge case and offer me some pointers.